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91.
Maria Cristina Righetti Patrizia Cinelli Laura Aliotta Elisa Bianchi Fabio Tricoli Maurizia Seggiani Andrea Lazzeri 《Polymer International》2022,71(1):47-56
This paper reports the thermal, morphological and mechanical properties of environmentally friendly poly(3-hydroxybutyrate) (PHB)/poly(butylene succinate) (PBS) and PHB/poly[(butylene succinate)-co-(butylene adipate)] (PBSA) blends, prepared by melt mixing. The blends are known to be immiscible, as also confirmed by the thermodynamic analysis here presented. A detailed quantification of the crystalline and amorphous fractions was performed, in order to interpret the mechanical properties of the blends. As expected, the ductility increased with increasing PBS or PBSA amount, but in parallel the decrease in the elastic modulus appeared limited. Surprisingly, the elastic modulus was found properly described by the rule of mixtures in the whole composition range, thus attesting mechanical compatibility between the two blend components. This unusual behavior has been explained as due to co-continuous morphology, present in a wide composition range, but also at the same time as the result of shrinkage occurring during sequential crystallization of the two components, which can lead to physical adhesion between matrix and dispersed phase. For the first time, the elastic moduli of the crystalline and mobile amorphous fractions of PBS and PBSA and of the mobile amorphous fraction of PHB at ambient temperature have been estimated through a mechanical modelling approach. © 2021 The Authors. Polymer International published by John Wiley & Sons Ltd on behalf of Society of Industrial Chemistry. 相似文献
92.
Self-adaptive surface measurements that can reduce data redundancy and improve time efficiency are in high demand in many fields of science and technology. For this purpose, a system implemented with Gaussian process (GP) adaptive sampling is developed. The non-parametric GP model is applied to reconstruct the topography and guide the subsequent sampling position, which is determined from the inference uncertainty estimation. A criterion is proposed to terminate the GP adaptive measurement automatically without any prior model or data of the topography. Experiments on typical surfaces validate the intelligence, adaptability, and high accuracy of the GP method along with the stabilization of the automatic iteration termination. Compared with traditional raster sampling, data redundancy is reduced and the time efficiency is improved without sacrificing the surface reconstruction accuracy. The proposed method can be implemented in other systems with similar measurement principles, thus benefitting surface characterizations. 相似文献
93.
锂电池是LWD仪器正常工作的动力来源,是仪器的心脏。仪器出井后,需要在井口读取数据,当锂电池的电量接近耗尽时,会导致数据读取失败的问题。该问题处理不当,会造成长期占用井口,影响钻井时效,严重时还可能会因短路造成昂贵的LWD仪器损坏。锂电池的临界电压问题暴露了该仪器的设计缺陷,在此通过技术方法充分利用INSITE系统本身提供的功能,绕过其设计缺陷将问题解决。 相似文献
94.
The fashionable Parr–Pearson (PP) atoms-in-molecule/bonding (AIM/AIB) approach for determining the exchanged charge necessary for acquiring an equalized electronegativity within a chemical bond is refined and generalized here by introducing the concepts of chemical power within the chemical orthogonal space (COS) in terms of electronegativity and chemical hardness. Electronegativity and chemical hardness are conceptually orthogonal, since there are opposite tendencies in bonding, i.e., reactivity vs. stability or the HOMO-LUMO middy level vs. the HOMO-LUMO interval (gap). Thus, atoms-in-molecule/bond electronegativity and chemical hardness are provided for in orthogonal space (COS), along with a generalized analytical expression of the exchanged electrons in bonding. Moreover, the present formalism surpasses the earlier Parr–Pearson limitation to the context of hetero-bonding molecules so as to also include the important case of covalent homo-bonding. The connections of the present COS analysis with PP formalism is analytically revealed, while a numerical illustration regarding the patterning and fragmentation of chemical benchmarking bondings is also presented and fundamental open questions are critically discussed. 相似文献
95.
Yuan Liu Baodong Chen Wei Li Lulu Zu Wei Tang Zhong Lin Wang 《Advanced functional materials》2021,31(38):2104770
A sustainable power source is a key technical challenge for practical applications of electrically responsive soft robots, especially the required voltage is over several thousand volts. Here, a practicable new technology, triboelectric soft robot (TESR) system with the primary characteristics of power source from mechanical energy, is developed. At its heart is TESR with bioinspired architectures made of soft-deformable body and two triboelectric adhesion feet, which is driven and accurately controlled through triboelectric effect, while reaching maximum crawling speeds of 14.9 mm s−1 on the acrylic surface. The characteristics of the TESR, including displacement and force, are tested and simulated under the power of a rotary freestanding triboelectric nanogenerator (RF-TENG). Crawling of TESR is successfully realized on different materials surfaces and different angle slopes under the driven of RF-TENG. Furthermore, a real-time visual monitoring platform, in which TESR carries a micro camera to transmit images in a long narrow tunnel, is also achieved successfully, indicating that it can be used for fast diagnosis in an area inaccessible to human beings in the future. This study offers a new insight into the sustainable power source technologies suitable for electrically responsive soft robots and contributes to expanding the applicability of TENGs. 相似文献
96.
以微型土压平衡(Earth Pressure Balance,EPB)盾构机推进液压系统作为研究对象,介绍了推进系统的工作原理,对混入空气后的油液黏度和有效体积弹性模量进行分析,建立了推进系统数学模型,并对混入不同百分比空气的系统进行仿真运算,得到了液压缸位移响应和速度响应随系统含气量变化的关系。研究表明:随着液压系统空气含量的增加,液压缸位移响应发生迟滞,速度响应变慢,液压缸在运动时产生振动。结合各液压元件工作原理,依次对实际盾构机推进系统元件进行排气,最终排除了液压系统中混入的空气,为实现盾构机平稳推进提供了理论依据。 相似文献
97.
传统通信模拟系统设计较为复杂,导致模拟过程消耗能量较大,不能准确模拟稳频通信质量。因此,提出基于Matlab的量子激光雷达稳频通信模拟系统。由于振荡器是雷达形成初始信号源的基础,通过分析振荡电路与相位噪声,获得相位噪声函数与通信频率存在的关系;为确保通信过程的稳定,将准确性与稳定性作为信号质量的评价指标,并采用锁频环稳频技术计算频率偏移程度,根据PID控制算法控制频率,量子激光雷达稳频通信;利用Matlab确定激光器、探测器等硬件组成结构,通过时序与数字阵列的设置完成模拟系统设计。仿真结果表明所提系统结构简便、性能稳定,能够真实模拟出稳频通信的信号质量。 相似文献
98.
以某大型钢结构制造企业为例,通过对产量分布、质量控制、劳动效率等基本数据的分析,研判外协生产管理体系方面存在的问题,从组织形态、管理模式、职能管理等多个维度提出了可行性建议,可为同类型钢结构制造企业提供经验借鉴。 相似文献
99.
马尔可夫跳变线性系统(MJLS)是一种具有多个模态的随机系统,系统在各个模态之间的跳变转移由一组马尔可夫链来决定。MJLS模型因其在表示过程中可以产生突变而更能精确的描述实际工程应用中的系统。近年来,MJLS的最优控制问题成为了研究的热点,动态规划、极大值原理以及线性矩阵不等式等成为了解决此类问题的主流方法。本文对MJLS最优控制领域的研究现状进行了综述。分别对一般情况下、带有噪声的情况下、带有时滞的情况下以及某些特定情况下的MLJS最优控制问题的国内外研究现状进行论述。最后进行了总结并提出MJLS最优控制领域未来值得关注的研究方向。 相似文献
100.
随着基于位置服务(Location Based Services,LBS)的发展与智能移动设备的普及,室内定位算法与系统受到了广泛研究与关注。为提高室内定位精度、增强系统鲁棒性,提出了基于多边限定的fingerprint定位方法。基于Wi-Fi RSSI(Received Signal Strength Indication)信号处理建立离线fingerprint数据库;通过对拟合距离-RSSI函数分析,提出了多边限定的方法确定一个最佳参考点(Reference Point,RP)集合,缩小在线定位阶段的搜索范围。在此基础上,再利用fingerprint定位方法进行定位。此外,实现了基于提出方法的室内定位系统原型用于算法性能评估。通过大量真实场景实验分析、验证了相较于传统fingerprint方法,基于多边限定的fingerprint定位方法能有效提高室内定位精度,增强系统鲁棒性。 相似文献